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1632.07

S

Sulfur

Element 16 · Reactive nonmetal

Sulfur (S)

Sulfur is a bright yellow nonmetal found near volcanoes and hot springs. Sulfuric acid, made from it, is the world’s most produced industrial chemical.

Key properties

Atomic mass
32.07
u
Electron configuration
[Ne] 3s2 3p4
Melting point
115.2 °C
388.36 K
Boiling point
444.6 °C
717.75 K
Density
2.067 g/cm³
Electronegativity
2.58
Pauling
Atomic radius
180 pm
van der Waals
1st ionisation energy
10.36 eV

Compare with every element:Electronegativity chartAtomic radius chartIonisation energy chartDensity chart of the elementsMelting point chartElectron configuration chart

Did you know?

Notable facts about sulfur

  1. 01

    Pure sulfur has no smell — the “rotten egg” odour comes from hydrogen sulfide and other compounds.

  2. 02

    Sulfur burns with a blue flame and gives off choking sulfur dioxide.

  3. 03

    Io, a moon of Jupiter, is coloured yellow and orange by sulfur from its volcanoes.

Applications

What is sulfur used for?

  • Sulfuric acid production
  • Vulcanising rubber
  • Fungicides and fertilisers
  • Gunpowder

History

Discovery & name origin

Discovered by

Known since antiquity

Year

Prehistoric

Where

Known since antiquity

Name origin

Latin sulfur; the Bible calls it brimstone, “burning stone”.

Atomic structure

Atomic properties

Atomic number
16
Atomic mass
32.07 u
Group
16
Period
3
Block
p-block
Electron configuration
[Ne] 3s2 3p4
Full configuration
1s2 2s2 2p6 3s2 3p4
Electrons per shell
2, 8, 6
Electronegativity (Pauling)
2.58
Electron affinity
2.077 eV
Atomic radius (van der Waals)
180 pm
Stable isotopes
4

Oxidation states

Highlighted: common oxidation states (+6, +4, -2).

Successive ionisation energies

Energy to remove each electron in turn (kJ/mol). Big jumps show where a new, inner shell begins.

  1. 1st999.6
  2. 2nd2,252
  3. 3rd3,357
  4. 4th4,556
  5. 5th7,004.3
  6. 6th8,495.8
  7. 7th27,107
  8. 8th31,719

Physical

Physical properties & colour

State at 20 °C
Solid
Melting point
388.36 K · 115.2 °C · 239.4 °F
Boiling point
717.75 K · 444.6 °C · 832.3 °F
Density
2.067 g/cm³
Molar heat capacity
22.75 J/(mol·K)
Appearance
Lemon yellow sintered microcrystals
CPK model colour

The CPK colour is the convention used for this element’s atoms in molecular models.

FAQ

Sulfur questions

What is S on the periodic table?

S is the symbol for sulfur, element 16 on the periodic table. It sits in group 16, period 3, in the reactive nonmetal category, and has an atomic mass of 32.07.

What is the atomic number of sulfur?

Sulfur has atomic number 16, so every sulfur atom has 16 protons in its nucleus. Its symbol is S and its atomic mass is 32.07.

Who discovered sulfur?

Sulfur has been known since antiquity (Prehistoric); no single discoverer is credited. The name comes from Latin sulfur; the Bible calls it brimstone, “burning stone”.

What is sulfur used for?

Sulfur is used for: sulfuric acid production; vulcanising rubber; fungicides and fertilisers; gunpowder.

Is sulfur a metal?

No. Sulfur is classed as a reactive nonmetal.

What is the electron configuration of sulfur?

The electron configuration of sulfur is [Ne] 3s2 3p4. Its 16 electrons are arranged in shells as 2, 8, 6.