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1735.45

Cl

Chlorine

Element 17 · Halogen

Chlorine (Cl)

Chlorine is a toxic yellow-green halogen gas. Combined with sodium, it forms table salt; on its own it is a powerful disinfectant.

  • Halogen
  • Period 3
  • Group 17
  • p-block
  • gas at room temperature

Key properties

Atomic mass
35.45
u
Electron configuration
[Ne] 3s2 3p5
Melting point
-101.5 °C
171.65 K
Boiling point
-34 °C
239.11 K
Density
3.214 g/L
Electronegativity
3.16
Pauling
Atomic radius
175 pm
van der Waals
1st ionisation energy
12.968 eV

Compare with every element:Electronegativity chartAtomic radius chartIonisation energy chartDensity chart of the elementsMelting point chartElectron configuration chart

Did you know?

Notable facts about chlorine

  1. 01

    Chlorinating drinking water is one of the biggest public-health advances in history.

  2. 02

    Chlorine gas was used as a weapon in World War I.

  3. 03

    Scheele thought it was a compound; Davy proved it was an element in 1810.

Applications

What is chlorine used for?

  • Water purification
  • PVC plastic
  • Bleach and disinfectants
  • Pharmaceuticals

History

Discovery & name origin

Year

1774

Where

Sweden

Name origin

Greek chloros, “pale green” — named by Humphry Davy for the gas’s colour.

Atomic structure

Atomic properties

Atomic number
17
Atomic mass
35.45 u
Group
17
Period
3
Block
p-block
Electron configuration
[Ne] 3s2 3p5
Full configuration
1s2 2s2 2p6 3s2 3p5
Electrons per shell
2, 8, 7
Electronegativity (Pauling)
3.16
Electron affinity
3.617 eV
Atomic radius (van der Waals)
175 pm
Stable isotopes
2

Oxidation states

Highlighted: common oxidation states (+7, +5, +1, -1).

Successive ionisation energies

Energy to remove each electron in turn (kJ/mol). Big jumps show where a new, inner shell begins.

  1. 1st1,251.2
  2. 2nd2,298
  3. 3rd3,822
  4. 4th5,158.6
  5. 5th6,542
  6. 6th9,362
  7. 7th11,018
  8. 8th33,604

Physical

Physical properties & colour

State at 20 °C
Gas
Melting point
171.65 K · -101.5 °C · -150.7 °F
Boiling point
239.11 K · -34 °C · -29.3 °F
Density
3.214 g/L
Molar heat capacity
—
Appearance
Pale yellow-green gas
CPK model colour

The CPK colour is the convention used for this element’s atoms in molecular models.

FAQ

Chlorine questions

What is Cl on the periodic table?

Cl is the symbol for chlorine, element 17 on the periodic table. It sits in group 17, period 3, in the halogen category, and has an atomic mass of 35.45.

What is the atomic number of chlorine?

Chlorine has atomic number 17, so every chlorine atom has 17 protons in its nucleus. Its symbol is Cl and its atomic mass is 35.45.

Who discovered chlorine?

Chlorine was discovered by Carl Wilhelm Scheele in 1774 (Sweden). The name comes from Greek chloros, “pale green” — named by Humphry Davy for the gas’s colour.

What is chlorine used for?

Chlorine is used for: water purification; PVC plastic; bleach and disinfectants; pharmaceuticals.

Is chlorine a metal?

No. Chlorine is classed as a halogen.

What is the electron configuration of chlorine?

The electron configuration of chlorine is [Ne] 3s2 3p5. Its 17 electrons are arranged in shells as 2, 8, 7.