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37

Li

Lithium

Element 3 · Alkali metal

Lithium (Li)

Lithium is the lightest metal and the least dense solid element. Soft and silvery, it powers most of the world’s rechargeable batteries.

Key properties

Atomic mass
7
u
Electron configuration
[He] 2s1
Melting point
180.5 °C
453.65 K
Boiling point
1,341.9 °C
1,615 K
Density
0.534 g/cm³
Electronegativity
0.98
Pauling
Atomic radius
182 pm
van der Waals
1st ionisation energy
5.392 eV

Compare with every element:Electronegativity chartAtomic radius chartIonisation energy chartDensity chart of the elementsMelting point chartElectron configuration chart

Did you know?

Notable facts about lithium

  1. 01

    Lithium is so light that it floats on water — and on oil, which is how it is often stored.

  2. 02

    It is one of only three elements made in the Big Bang, alongside hydrogen and helium.

  3. 03

    Lithium salts have been used since 1949 as a mood stabiliser to treat bipolar disorder.

Applications

What is lithium used for?

  • Lithium-ion batteries
  • Psychiatric medication
  • Heat-resistant glass and ceramics
  • Lubricating greases

History

Discovery & name origin

Year

1817

Where

Sweden

Name origin

Greek lithos, “stone” — it was discovered in a mineral, unlike sodium and potassium found in plant ash.

Atomic structure

Atomic properties

Atomic number
3
Atomic mass
7 u
Group
1
Period
2
Block
s-block
Electron configuration
[He] 2s1
Full configuration
1s2 2s1
Electrons per shell
2, 1
Electronegativity (Pauling)
0.98
Electron affinity
0.618 eV
Atomic radius (van der Waals)
182 pm
Stable isotopes
2

Oxidation states

Highlighted: common oxidation states (+1).

Successive ionisation energies

Energy to remove each electron in turn (kJ/mol). Big jumps show where a new, inner shell begins.

  1. 1st520.2
  2. 2nd7,298.1
  3. 3rd11,815

Physical

Physical properties & colour

State at 20 °C
Solid
Melting point
453.65 K · 180.5 °C · 356.9 °F
Boiling point
1,615 K · 1,341.9 °C · 2,447.3 °F
Density
0.534 g/cm³
Molar heat capacity
24.86 J/(mol·K)
Appearance
Silvery-white
CPK model colour

The CPK colour is the convention used for this element’s atoms in molecular models.

FAQ

Lithium questions

What is Li on the periodic table?

Li is the symbol for lithium, element 3 on the periodic table. It sits in group 1, period 2, in the alkali metal category, and has an atomic mass of 7.

What is the atomic number of lithium?

Lithium has atomic number 3, so every lithium atom has 3 protons in its nucleus. Its symbol is Li and its atomic mass is 7.

Who discovered lithium?

Lithium was discovered by Johan August Arfwedson in 1817 (Sweden). The name comes from Greek lithos, “stone” — it was discovered in a mineral, unlike sodium and potassium found in plant ash.

What is lithium used for?

Lithium is used for: lithium-ion batteries; psychiatric medication; heat-resistant glass and ceramics; lubricating greases.

Is lithium a metal?

Yes. Lithium is a alkali metal, one of the metallic elements.

What is the electron configuration of lithium?

The electron configuration of lithium is [He] 2s1. Its 3 electrons are arranged in shells as 2, 1.