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4091.22

Zr

Zirconium

Element 40 · Transition metal

Zirconium (Zr)

Zirconium is a strong, corrosion-resistant metal that barely absorbs neutrons, making it ideal for nuclear fuel cladding.

Key properties

Atomic mass
91.22
u
Electron configuration
[Kr] 4d2 5s2
Melting point
1,854.9 °C
2,128 K
Boiling point
4,408.9 °C
4,682 K
Density
6.52 g/cm³
Electronegativity
1.33
Pauling
Atomic radius
186 pm
van der Waals
1st ionisation energy
6.634 eV

Compare with every element:Electronegativity chartAtomic radius chartIonisation energy chartDensity chart of the elementsMelting point chartElectron configuration chart

Did you know?

Notable facts about zirconium

  1. 01

    Zircon crystals from Western Australia are about 4.4 billion years old — the oldest known pieces of Earth.

  2. 02

    Cubic zirconia is a popular, inexpensive diamond substitute.

  3. 03

    About 90% of zirconium metal is used in nuclear reactors.

Applications

What is zirconium used for?

  • Nuclear fuel rod cladding
  • Ceramics and refractories
  • Cubic zirconia gems
  • Dental crowns

History

Discovery & name origin

Year

1789

Where

Germany

Name origin

Persian zargun, “gold-coloured”, from the gemstone zircon.

Atomic structure

Atomic properties

Atomic number
40
Atomic mass
91.22 u
Group
4
Period
5
Block
d-block
Electron configuration
[Kr] 4d2 5s2
Full configuration
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d2
Electrons per shell
2, 8, 18, 10, 2
Electronegativity (Pauling)
1.33
Electron affinity
0.426 eV
Atomic radius (van der Waals)
186 pm
Stable isotopes
4

Oxidation states

Highlighted: common oxidation states (+4).

Successive ionisation energies

Energy to remove each electron in turn (kJ/mol). Big jumps show where a new, inner shell begins.

  1. 1st640.1
  2. 2nd1,270
  3. 3rd2,218
  4. 4th3,313
  5. 5th7,752
  6. 6th9,500

Physical

Physical properties & colour

State at 20 °C
Solid
Melting point
2,128 K · 1,854.9 °C · 3,370.7 °F
Boiling point
4,682 K · 4,408.9 °C · 7,967.9 °F
Density
6.52 g/cm³
Molar heat capacity
25.36 J/(mol·K)
Appearance
Silvery white
CPK model colour

The CPK colour is the convention used for this element’s atoms in molecular models.

FAQ

Zirconium questions

What is Zr on the periodic table?

Zr is the symbol for zirconium, element 40 on the periodic table. It sits in group 4, period 5, in the transition metal category, and has an atomic mass of 91.22.

What is the atomic number of zirconium?

Zirconium has atomic number 40, so every zirconium atom has 40 protons in its nucleus. Its symbol is Zr and its atomic mass is 91.22.

Who discovered zirconium?

Zirconium was discovered by Martin Heinrich Klaproth in 1789 (Germany). The name comes from Persian zargun, “gold-coloured”, from the gemstone zircon.

What is zirconium used for?

Zirconium is used for: nuclear fuel rod cladding; ceramics and refractories; cubic zirconia gems; dental crowns.

Is zirconium a metal?

Yes. Zirconium is a transition metal, one of the metallic elements.

What is the electron configuration of zirconium?

The electron configuration of zirconium is [Kr] 4d2 5s2. Its 40 electrons are arranged in shells as 2, 8, 18, 10, 2.